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Chiral superbases: the proton affinities of 1- and 2-aza[6]helicene in the gas phase

✍ Scribed by Jana Roithová; Detlef Schröder; Jiří Míšek; Irena G. Stará; Ivo Starý

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
182 KB
Volume
42
Category
Article
ISSN
1076-5174

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✦ Synopsis

Abstract

The proton affinities (PAs) of 1‐ and 2‐azahelicene were determined using various mass spectrometric techniques and complementary results from density functional theory. With PAs of about 1000 kJ mol^−1^, the helical backbone of both compounds offer promising perspectives for future research on enantioselective reactions of these helical nitrogen bases. Copyright © 2007 John Wiley & Sons, Ltd.

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