𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Chiral Sulfoxide-Olefin Ligands: Completely Switchable Stereoselectivity in Rhodium-Catalyzed Asymmetric Conjugate Additions

✍ Scribed by Guihua Chen; Jiangyang Gui; Dr. Liangchun Li; Prof. Dr. Jian Liao


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
389 KB
Volume
50
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.

✦ Synopsis


www.angewandte.org residue was purified by flash chromatography on silica gel with petroleum ether/ethyl acetate 20:1 as eluent to afford the adduct.


📜 SIMILAR VOLUMES


tert-Butanesulfinylphosphines: Simple Ch
✍ Feng Lang; Dong Li; Junmin Chen; Jun Chen; Liangchun Li; Linfeng Cun; Jin Zhu; J 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 191 KB 👁 1 views

## Abstract An efficient rhodium complex catalyst system was developed by using a class of simple __tert__‐butanesulfinylphosphines as bidentate ligands, which solely bear sulfur chirality and combine the advantages of both sulfoxide and phosphine ligands. Excellent activities (in 0.5 hour, up to 9