2,3-Di-O-pentyl-6-O-tert-butyldimethylsilyl-b-cyclodextrin has been evaluated as an enantioselective stationary phase for capillary gas chromatography. Experimental results show a good enantioselectivity towards compounds with different functional groups (haloalkanes, alcohols, esters, terpenoids, a
✦ LIBER ✦
Chiral separation of γ-butyrolactone derivatives by gas chromatography on 2,3-di-O-methyl-6-O-tert.-butyldimethylsilyl-β-cyclodextrin
✍ Scribed by Maria da Conceição K.V. Ramos; Lis H.P Teixeira; Francisco R de Aquino Neto; Eliezer J Barreiro; Carlos R Rodrigues; Carlos A.M Fraga
- Book ID
- 108339198
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- English
- Weight
- 654 KB
- Volume
- 985
- Category
- Article
- ISSN
- 1873-3778
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In previous papers, 2,6-di-O-methyl-3-O-pentyl-~-cyclodextrin (CD) was demonstrated to be successful in separating volatile compounds, while avoiding the drawbacks of 2,3,6-tri-O-methyl-P-CD in terms of column stability and operating temperature. Since a CD chiral selector of universal use has not y