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Chiral recognition of diastereomeric 6-cedrols by vibrational circular dichroism

✍ Scribed by Bárbara Gordillo-román; Jorge Camacho-ruiz; María A. Bucio; Pedro Joseph-Nathan

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 596 KB
Volume: 24
Category: Article
ISSN: 0899-0042
DOI: 10.1002/chir.21036

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✦ Synopsis

Abstract

The use of vibrational circular dichroism spectroscopy for the chiral recognition of the two epimers of 6‐cedrol, tricyclic sesquiterpenes, which contains oxygen as the heaviest atom, is shown. Bands in the 1500–850 cm^−1^ region of the spectra were analyzed to calculate the anisotropy factors (g), which provided the regions of maximum circular dichroism effect for each epimer. Chirality, 2012. © 2011 Wiley Periodicals, Inc.

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