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Chiral Primary Amine Catalyzed Asymmetric Epoxidation of α-Substituted Acroleins

✍ Scribed by Jiuyuan Li; Niankai Fu; Long Zhang; Pengxin Zhou; Sanzhong Luo; Jin-Pei Cheng

Publisher: John Wiley and Sons
Year: 2010
Tongue: English
Weight: 428 KB
Volume: 2010
Category: Article
ISSN: 1434-193X
DOI: 10.1002/ejoc.201001117

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## Abstract The direct organocatalytic enantioselective epoxidation of α,β‐unsaturated aldehydes with different peroxides is presented. Proline, chiral pyrrolidine derivatives, and amino acid‐derived imidazolidinones catalyze the asymmetric epoxidation of α,β‐unsaturated aldehydes. In particular, p