## Abstract A simple catalytic system that uses commercially available manganese(II) perchlorate as the catalyst and peracetic acid as the oxidant is found to be very effective in the epoxidation of aliphatic terminal alkenes with high product selectivity at ambient temperature. Many terminal alken
✦ LIBER ✦
Simple Primary Anilines as Iminium Catalysts for the Epoxidation of α-Substituted Acroleins
✍ Scribed by Anniina Erkkilä; Petri M. Pihko; Melanie-Rose Clarke
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 91 KB
- Volume
- 349
- Category
- Article
- ISSN
- 1615-4150
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A series of transition metal substituted polyfluorooxometalates (PFOM) [M(L)H2F6NaW17)55]q-, M= Zn2+ , Co2+, Mn2+, Fc2+, Ru2+, Ni2+ and V5+ and L=H2O, O2-, of quasi-Wells-Dawson structure, was synthesized. In the series prepared, only the nickel-substituted polyfluorooxometalate was capable of catal