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Chiral phosphine complexes of ruthenium(II) arenes

✍ Scribed by Deryn E. Fogg; Brian R. James

Book ID
107812589
Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
313 KB
Volume
462
Category
Article
ISSN
0022-328X

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πŸ“œ SIMILAR VOLUMES

Catalytic asymmetric hydrogenation of cy
Catalytic asymmetric hydrogenation of cyclic anhydrides using ruthenium (II) chiral phosphine complex
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Optically active y-and d-lactones are obtained by the hydrogenation of five-and six-membered cyclic anhydrides using a Ru(I1) complex with chiral phosphine ligand, DIOP, as a catalyst. Catalytic asymmetric hydrogenation with transition metal complexes has stereoselective addition of a hydrogen molec

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Ruthenium-arene complexes containing phosphines with pendent aryl groups [RuCI2(rl6-p-cymene) -(PCy2(CH2)3Ar)], Ar = C6H5 and 3,5-(CH3)2-C6H 3 (1 and 3), and the resulting chelating complexes [RuC12(PCy2-(CH2)3-'q6-Ar)] (2 and 4) mediate the cyclopropanation of olefins with ethyl diazoacetate. Compa