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Catalytic asymmetric hydrogenation of cyclic anhydrides using ruthenium (II) chiral phosphine complex

✍ Scribed by Kohtaro Osakada; Masamichi Obana; Takao Ikariya; Masahiko Saburi; Sadao Yoshikawa

Publisher: Elsevier Science
Year: 1981
Tongue: French
Weight: 237 KB
Volume: 22
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)82939-7

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✦ Synopsis

Optically active y-and d-lactones are obtained by the hydrogenation of five-and six-membered cyclic anhydrides using a Ru(I1) complex with chiral phosphine ligand, DIOP, as a catalyst. Catalytic asymmetric hydrogenation with transition metal complexes has stereoselective addition of a hydrogen molecule to either of the prochiral faces of a double bond, such as C=C, C=O, and C=N, using transition metal complexes with chiral phosphine ligands as catalyst. Little was known about

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