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Chiral phosphinamides: new catalysts for the asymmetric reduction of ketones by borane

โœ Scribed by Burns, Barry; King, N. Paul; Tye, Heather; Studley, John R.; Gamble, Mark; Wills, Martin

Book ID
120541139
Publisher
Royal Society of Chemistry
Year
1998
Weight
210 KB
Volume
6
Category
Article
ISSN
1472-7781

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๐Ÿ“œ SIMILAR VOLUMES

ChemInform Abstract: A Novel Phosphinami
ChemInform Abstract: A Novel Phosphinamide Catalyst for the Asymmetric Reduction of Ketones by Borane.
โœ M. P. GAMBLE; A. R. C. SMITH; M. WILLS ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 31 KB ๐Ÿ‘ 2 views

A Novel Phosphinamide Catalyst for the Asymmetric Reduction of Ketones by Borane. -The novel phosphinamide ("cat.") is a readily available, robust, versatile and recoverable reagent for the catalytic asymmetric reduction of ketones by borane. -(GAMBLE, M.

Phosphinamides catalysts containing a st
Phosphinamides catalysts containing a stereogenic phosphorus atom for the asymmetric reduction of ketones by borane
โœ Barry Burns; Mark P. Gamble; Athene R.C. Simm; John R. Studley; Nathaniel W. Alc ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 419 KB

The effect of the configuration of the phosphorus atom in phosphinamide reduction catalysts has been studied through the preparation and use of a series of catalysts containing stereogenic phosphorus atoms of known configuration. The conclusion of this work is that a stereogenic centre at phosphorus