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Chiral O,N-bis(diphenylphosphino)aminoalkanols as ligands for enantioselective metal complex hydrogenation catalysts

✍ Scribed by G. Pracejus; H. Pracejus


Publisher
Elsevier Science
Year
1984
Weight
217 KB
Volume
24
Category
Article
ISSN
0304-5102

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✍ Changqing Wang; Guoqiang Yang; Jing Zhuang; Wanbin Zhang 📂 Article 📅 2010 🏛 Elsevier Science 🌐 French ⚖ 350 KB

A class of atropisomeric diphosphine ligands with a wide range of dihedral angles has been developed. X-ray study of the Pd(II) complexes of these ligands showed that as the bridge length increased, the dihedral angles and the ligand bite angles increased as well, while an excessive increase in brid