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Ruthenium Complexes Containing Chiral N-Donor Ligands as Catalysts in Acetophenone Hydrogen Transfer – New Amino Effect on Enantioselectivity

✍ Scribed by Montserrat Gómez; Susanna Jansat; Guillermo Muller; Gabriel Aullón; Miguel Angel Maestro

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
226 KB
Volume
2005
Category
Article
ISSN
1434-1948

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Water-Soluble Arene Ruthenium Complexes
Water-Soluble Arene Ruthenium Complexes Containing a trans-1,2-Diaminocyclohexane Ligand as Enantioselective Transfer Hydrogenation Catalysts in Aqueous Solution
✍ Jérôme Canivet; Gael Labat; Helen Stoeckli-Evans; Georg Süss-Fink 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 179 KB

## Abstract The cationic chloro complexes [(arene)Ru(H~2~N∩NH~2~)Cl]^+^ (1: arene = C~6~H~6~; 2: arene = __p__‐MeC~6~H~4~__i__Pr; 3: arene = C~6~Me~6~) have been synthesised from the corresponding arene ruthenium dichloride dimers and enantiopure (__R__,__R__ or __S__,__S__) __trans__‐1,2‐diaminocy

Water-Soluble Arene Ruthenium Complexes
Water-Soluble Arene Ruthenium Complexes Containing a trans-1,2-Diaminocyclohexane Ligand as Enantioselective Transfer Hydrogenation Catalysts in Aqueous Solution (Eur. J. Inorg. Chem. 22/2005)
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## Abstract **The cover picture shows** the postulated catalytic cycle for the pH‐dependent, enantioselective transfer hydrogenation of acetophenone to give phenylethanol in water, using formate as hydrogen donor and (arene)ruthenium(__trans__‐diaminocyclohexane) as chiral catalyst. This work illus