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Chiral olefin–sulfoxide as ligands for rhodium-catalyzed asymmetric conjugate addition of arylboronic acids to unsaturated esters

✍ Scribed by Xue, Feng; Wang, Dongping; Li, Xincheng; Wan, Boshun


Book ID
121245790
Publisher
Royal Society of Chemistry
Year
2013
Tongue
English
Weight
518 KB
Volume
11
Category
Article
ISSN
1477-0520

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## Abstract An efficient rhodium complex catalyst system was developed by using a class of simple __tert__‐butanesulfinylphosphines as bidentate ligands, which solely bear sulfur chirality and combine the advantages of both sulfoxide and phosphine ligands. Excellent activities (in 0.5 hour, up to 9