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Chiral N-Phosphonyl Imine Chemistry: Asymmetric Synthesis of α-Alkyl β-Amino Ketones by Reacting Phosphonyl Imines with Ketone-Derived Enolates

✍ Scribed by Teng Ai; Jianlin Han; Zhong-Xiu Chen; Guigen Li


Book ID
111368650
Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
118 KB
Volume
73
Category
Article
ISSN
1747-0277

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ChemInform Abstract: Chiral N-Phosphonyl
✍ Jianlin Han; Teng Ai; Guigen Li 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 43 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Chiral N-phosphonyl imine chemistry: asy
✍ Zhong-Xiu Chen; Teng Ai; Parminder Kaur; Guigen Li 📂 Article 📅 2009 🏛 Elsevier Science 🌐 French ⚖ 179 KB

Chiral N-phosphonyl imines attached by 1-naphthyl group were found to react with lithium malonate enolates smoothly to give chiral b-aminomalonates. Good yields and excellent diastereoselectivity were achieved for sixteen examples. The chiral auxiliary can be readily removed by treating with trifluo