Chiral Dirhodium(II) Catalysts with Orthometalated Aryl Phosphine Ligands: Synthesis and Application for Enantioselective C−H Insertion of α-Diazo Ketones
✍ Scribed by Estevan, Francisco; Herbst, Konrad; Lahuerta, Pascual; Barberis, Mario; Pérez-Prieto, Julia
- Book ID
- 126041172
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 119 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0276-7333
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Highly Enantioselective Construction of the Key Azetidin-2-ones for the Synthesis of Carbapenem Antibiotics via Intramolecular C-H Insertion Reactions of α-Methoxycarbonyl-α-diazoacetamides Catalyzed by Chiral Dirhodium(II) Carboxylates. -The title reaction of compounds (I) and (III) to afford bicy