Chiral Clusters in the Gas Phase
β Scribed by Maurizio Speranza
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 8 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
O (70 %, Cambridge Isotope Laboratories) was used for the isotopic studies. molecular-beam Fourier transform microwave spectrometer, [23, 24] with a General Valve (Series 9) pulsed nozzle of 0.8 mm orifice diameter, was used. The uncertainty of the frequency measurements is about 2 kHz and the full
Leuven (Belgium) [\*\*] The authors thank the Fonds der Chemischen Industrie and the Deutsche Forschungsgemeinschaft (SFB 546) for financial support, the Stichting voor Fundamenteel Onderzoek der Materie (FOM) for beamtime on FELIX, and the technical staff of FELIX for their assistance with the exp
Enantiodiscrimination of several chiral molecules, i.e. S-(+)-(s) vs R-(-)-2-butanol (r) and S-(+)-(s) vs R-(-)-2-butylamine (r), is obtained by two-color resonance-enhanced two-photon ionization time-of-flight (2cR2PI-TOF) spectroscopy of their supersonically expanded complexes with a suitable chro