Leuven (Belgium) [\*\*] The authors thank the Fonds der Chemischen Industrie and the Deutsche Forschungsgemeinschaft (SFB 546) for financial support, the Stichting voor Fundamenteel Onderzoek der Materie (FOM) for beamtime on FELIX, and the technical staff of FELIX for their assistance with the exp
Structure and Reactivity of Silicon Clusters in the Gas Phase
β Scribed by Dipl.-Chem. Thomas Lange; Dr. T. Patrick Martin
- Publisher
- John Wiley and Sons
- Year
- 1992
- Tongue
- English
- Weight
- 231 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0044-8249
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Ab initio density functional calculations for Na Pb, Li Pb, Na Pb , and n n n 4 Li Pb are reported. The abundance of Na Pb observed in gas-phase experiments is n 4 6 explained as a consequence of evaporative cooling, which stops at Na Pb because of the 6 high evaporation energy of this cluster. Insi
Approaches for analyzing kinetic and thermochemical data from the reactions of multiply charged ions are presented. A method for estimating the electrostatic repulsion in a multiply charged ion is described followed by examples of the potential energy surfaces for two representative reactions of mul
Novel cation-bound bi-radicals are generated in a chemical ionization source from either the stable free radical, 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO), or the phenoxyl radical and cations including carbonyl isocyanate, ( [ OCNCO' ] ), and, in one case, the proton. The dimeric cluster ions, m