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Chiral bicyclic keto lactones: determination of the absolute configuration by the study of chiroptical properties and chemical correlation

✍ Scribed by Sigitas Stončius; Ulf Berg; Eugenius Butkus


Book ID
108283796
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
441 KB
Volume
15
Category
Article
ISSN
0957-4166

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✍ Marc Lamshöft; Hans Schmickler; Franz-Josef Marner 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 137 KB 👁 1 views

## Abstract Hydroxyiridals − monocyclic triterpenoids − are found abundantly in sword lilies. They feature a homofarnesyl side chain that is hydroxylated at one of the allylic methylene groups, which gives rise to a chiral carbon atom. The absolute configuration of six hydroxyiridals from different