The reactions of Cr VI with nine biological and nonbiological thiols RSH in aqueous acetate buffer pH 5.60 have Ε½ y . been followed by an spectrophotometric method, and a relatively stable intermediate the thioester RSCrO has been 3 Ε½ . Ε½ . Ε½ . observed. The rate constants corresponding to the forma
Chiral base catalysis in the reaction of thiols with a quinone epoxide
β Scribed by Henk Pluim; Hans Wynberg
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 166 KB
- Volume
- 103
- Category
- Article
- ISSN
- 0165-0513
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