ChemInform Abstract: Enantioselective Ring Opening of Epoxides with Silicon Tetrachloride in the Presence of a Chiral Lewis Base.
β Scribed by S. E. DENMARK; P. A. BARSANTI; K.-T. WONG; R. A. STAVENGER
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 38 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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This paper reported a new class of diastereomerically pure ortho-methoxydiazaphosphonamide Lewis bases prepared from the corresponding o-hydroxyarylphosphonamides. These bases have been applied to the catalytic asymmetric ring opening of cyclooctene oxide with SiCl 4 . During the last weeks, I discl