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ChemInform Abstract: Chiral o-Methoxyaryldiazaphosphonamides — A New Class of Efficient Lewis Bases in the Catalytic Asymmetric Ring Opening of Cyclooctene Oxide with Silicon Tetrachloride.

✍ Scribed by Sebastien Reymond; Olivier Legrand; Jean Michel Brunel; Gerard Buono

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
33
Category
Article
ISSN
0931-7597

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Abstract

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Chiral o-Methoxyaryldiazaphosphonamides
Chiral o-Methoxyaryldiazaphosphonamides − A New Class of Efficient Lewis Bases in the Catalytic Asymmetric Ring Opening of Cyclooctene Oxide with Silicon Tetrachloride
✍ Gérard Buono 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 84 KB 👁 1 views

This paper reported a new class of diastereomerically pure ortho-methoxydiazaphosphonamide Lewis bases prepared from the corresponding o-hydroxyarylphosphonamides. These bases have been applied to the catalytic asymmetric ring opening of cyclooctene oxide with SiCl 4 . During the last weeks, I discl