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Chiral-Auxiliary-Mediated Asymmetric Synthesis of Tris-Heteroleptic Ruthenium Polypyridyl Complexes

โœ Scribed by Gong, Lei; Mulcahy, Seann P.; Harms, Klaus; Meggers, Eric

Book ID
126793429
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
514 KB
Volume
131
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES

The first asymmetric synthesis of chiral
The first asymmetric synthesis of chiral ruthenium tris(bipyridine) from racemic ruthenium bis(bipyridine) complexes
โœ Dusan Hesek; Yoshihisa Inoue; Hitoshi Ishida; Simon R.L Everitt; Michael G.B Dre ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 115 KB

The first 'one-pot' asymmetric synthesis of ruthenium tris(bipyridine) derivatives starting from corresponding racemic ruthenium bis(bipyridine) complexes is described. This is achieved through the stereocontrolled formation of reactive intermediates derived from (R)-(+)-or (S)-(-)-methyl p-tolyl su