The reaction rates of 2-chloro-3,5-dinitropyridine 1 with a series of arylthiolates 2a-h in methanol have been measured at 25Β°C. The products are the corresponding 2-thioaryl-3,5-dinitropyridine 3a-h. Good Hammett correlation with value Οͺ1.19 was obtained suggesting an elimination-addition mechanism
Chemoselectivity Reversals in Quinoxalines: The Reaction of 5-Chloro-6-Nitroquinoxaline with Nucleophiles
β Scribed by J. Nasielski; C. Moucheron; R. Nasielski-Hinkens
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 348 KB
- Volume
- 101
- Category
- Article
- ISSN
- 0037-9646
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The kinetics of the reaction of 2-chloro-3-nitropyridine (ortho-like) and 2-chloro-5-nitropyridine (para-like) with a series of aryloxide ions were studied in methanol at different temperatures. Plots of DH β versus DS β for both reactions gave good straight lines with isokinetic temperatures of 168
The kinetics of the reactions of 2-chloro-3-nitropyridine (ortho-like) and 5-nitro ( para-like) isomer with morpholine and piperidine were studied in methanol and benzene at several amine concentrations and temperatures in the range 25 -45Β°C. The data show that k 3-NO 2 /k 5-NO 2 ratios are less tha
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