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Chemoenzymatic Total Synthesis of the Phytotoxic Lactone Herbarumin III.

✍ Scribed by Samik Nanda

Publisher
John Wiley and Sons
Year
2005
Weight
9 KB
Volume
36
Category
Article
ISSN
0931-7597

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## Abstract The total synthesis of phytotoxic nonenolide herbarumin II (**1**) has been achieved by implementation of butane diacetal (BDA)‐desymmetrised glycolate building blocks. Three of the four stereogenic centres present in the key coupling fragments were generated from both enantiomeric form