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Chemoenzymatic synthesis of both enantiomers of 3-hydroxy- and 3-amino-3-phenylpropanoic acid

✍ Scribed by Varga, Annamaria; Zaharia, Valentin; Nógrádi, Mihály; Poppe, László

Book ID
121360924
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
545 KB
Volume
24
Category
Article
ISSN
0957-4166

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4-Oxo-3,4-dihydro-2-chromen-3-yl acetate is synthesized using manganese(III)acetate starting from 2,3-dihydro-4Hchromen-4-one. K 2 CO 3 mediated hydrolysis of 4-oxo-3,4-dihdro-2-chromen-3-yl acetate furnished 3-hydroxy-2,3-dihydro-4Hchromen-4-one in high yield.The enantioselective hydrolysis of (±)-