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Chemoenzymatic large-scale preparation of homochiral bicyclo[3.2.0]hept-2-en-6-one

✍ Scribed by Norbert Klempier; Kurt Faber; Herfried Griengl

Book ID: 105047138
Publisher: Springer Netherlands
Year: 1989
Tongue: English
Weight: 191 KB
Volume: 11
Category: Article
ISSN: 0141-5492
DOI: 10.1007/bf01044097

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Single crystal X-ray diffraction analysis of compounds A, B and, C helped us to assign the absolute configurations of the enantiomers of the bicyclo[3.2.0]hept-3-en-6-endo-ols 4-6. These bicyclic alcohols were easily obtained by: (i) stereoselective reductions of the bicyclo[3.2.0]hept-3-en-6-ones 1