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Chemo-, Regio-, and Stereoselective Cyclization of 1,3-Bis(trimethylsilyloxy)-1,3-butadienes with Functionalized Epoxides

✍ Scribed by Peter Langer; Tobias Eckardt


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
98 KB
Volume
39
Category
Article
ISSN
0044-8249

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Domino reactions facilitate the rapid assembly of complex products in a one-pot process. [1] Despite the simplicity of the idea, domino cyclizations of 1,3-dicarbonyl dianions [2] with dielectrophiles are relatively rare. [3] As a result of their high negative charge density, ambident dianions are v