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Chemo- and Stereoselective Monobenzoylation of 1,2-Diols Catalyzed by Organotin Compounds

✍ Scribed by Iwasaki, Fumiaki; Maki, Toshihide; Onomura, Osamu; Nakashima, Waka; Matsumura, Yoshihiro


Book ID
127084672
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
117 KB
Volume
65
Category
Article
ISSN
0022-3263

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Efficient Oxidation of 1,2-Diols into Ξ±-
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## Abstract **Get selective!** A selective oxidation of 1,2‐diols to α‐hydroxyketones catalyzed by organotin compounds has been developed (see scheme). Invaluable chemo‐ and stereoselectivity were found in the reaction. The catalytic system has been achieved by electrochemical and chemical oxidatio