Chemo- and regioselective oxidation of adamantyl derivatives by dioxiranes
β Scribed by Lucia D'Accolti; Ping Kang; Saeed Khan; Ruggero Curci; Christopher S. Foote
- Book ID
- 104251294
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- French
- Weight
- 103 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Methyl(trifluoromethyl) dioxirane (1) gives direct chemo-and regioselective oxidation of methyleneadamantane oxide (2) and isopropylideneadamantane oxide (3) in high yield under mild conditions.
π SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
## Abstract A convenient and facile chemoβ and regioselective oxidation of the allylic methylene group in a 2βphospholene ring system afforded the novel carbonyl derivatives of 2βphospholenes (**__2aβi__**). The method gives high conversion and selectivity in the formation of allylic ketones. The a
Regioselective Intramolecular Oxidation of Unactivated C-H Bonds by Dioxiranes Generated in situ. -It is a novel method for selective oxidation of unactivated C-H bonds at the Ξ΄ side of ketones. -(YANG, D.;