The chemistry of trifluorosulfinic acid
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H.W. Roesky; G. Holtschneider
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Article
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1976
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Elsevier Science
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English
β 288 KB
The preparation of NaS02CF3, KS02CF3 and AgS02CF3 from HS02CF3 and the corresponding carbonates is described. CF3S(0)N[Si(CH3)3]2 or CF3S(0)NHSi(CH3)3 react with SOC12 to form CF3S(0)N=S=0. A compound with two sulfur atoms in oxidation state +4. The reaction products of CF3S(0)NC0 with CHSOH, CHICOO