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Chemistry of trifluorothiolacetic acid and its derivatives. I

✍ Scribed by Rochat, W. V.; Gard, Gary L.


Book ID
126210617
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
630 KB
Volume
34
Category
Article
ISSN
0022-3263

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The chemistry of trifluorosulfinic acid
✍ H.W. Roesky; G. Holtschneider πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 288 KB

The preparation of NaS02CF3, KS02CF3 and AgS02CF3 from HS02CF3 and the corresponding carbonates is described. CF3S(0)N[Si(CH3)3]2 or CF3S(0)NHSi(CH3)3 react with SOC12 to form CF3S(0)N=S=0. A compound with two sulfur atoms in oxidation state +4. The reaction products of CF3S(0)NC0 with CHSOH, CHICOO