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Chemistry of the trans-trimethylenenorbornene ring system. II. Thermal rearrangement to the cis,anti, cis-tricyclo[5.3.0.02,6]decane system

✍ Scribed by Clemans, George B.


Book ID
126423387
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
430 KB
Volume
38
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES


Intramolecular photocyclization of cis,
✍ Arnon Shani πŸ“‚ Article πŸ“… 1972 πŸ› Elsevier Science 🌐 French βš– 131 KB

The transannular photocyclization of the cis,cis-cyclodecs-1,6+lienes to the tricyolo 5.3.0.02p6 --C 3 decane (1) may be explained due to the proximity in space of the two double bonds in the ~~hamnocks conformation I (2). Hence, in an intramolecular photocyclization of the isomeric trans,trans,cycl