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ChemInform Abstract: C-B-A-D Approach to Brassinosteroids: Generation of the cis-anti-trans A-B-C Ring System.

✍ Scribed by T. ZOLLER; D. UGUEN; A. DE CIAN; J. FISCHER; S. SABLE

Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
28
Category
Article
ISSN
0931-7597

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An IMDA Approach to Tigliane and Daphnane Diterpenoids: Generation of the Tetracyclic Ring System of the Tiglianes. -The tetracyclic compound (V) representing the ring system of phorbol and other tigliane diterpenes is prepared using an unusual intramolecular Diels-Alder reaction of (I) followed by