Ab initio MO calculations (MP2/6-311 G\*\*//HF/6-311 G\*\*) have been performed for several isomers (including rotamers) of Me,S,O and Me,S,O,. MeS(0)SSMe exists as five ro- tamers; the most stable form (la) has a helical backbone CSSSC with S-S bond lengths of 206.0 (S"S") and 212.4 pm (S"S"'). The
โฆ LIBER โฆ
Chemistry of the S=O bond. 13. Structures of isomers 1 (I) and 2 (II) of 4-methyl-1,3,2-dioxathiane 2-oxide and 1,3,2-dioxathiepane 2-oxide (III) at 256, 240 and 228 K
โ Scribed by Hellier, D. G. ;Luger, P. ;Buschmann, J.
- Book ID
- 114515186
- Publisher
- International Union of Crystallography
- Year
- 1996
- Tongue
- English
- Weight
- 403 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0108-7681
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