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ChemInform Abstract: Sulfur Compounds. Part 193. Oxidation Products of Organic Trisulfanes: Molecular Structures and Energies of Various Isomers of the Dimethyltrisulfane Oxides Me2S3O and Me2S3O2 and of 1,3-tBu2S3O2.

✍ Scribed by R. STEUDEL; Y. DROZDOVA


Book ID
112040928
Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
27
Category
Article
ISSN
0931-7597

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Oxidation Products of Organic Trisulfane
✍ Prof. Dr. Ralf Steudel; Dr. Yana Drozdova πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 898 KB

Ab initio MO calculations (MP2/6-311 G\*\*//HF/6-311 G\*\*) have been performed for several isomers (including rotamers) of Me,S,O and Me,S,O,. MeS(0)SSMe exists as five ro- tamers; the most stable form (la) has a helical backbone CSSSC with S-S bond lengths of 206.0 (S"S") and 212.4 pm (S"S"'). The