Oxidation Products of Organic Trisulfane
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Prof. Dr. Ralf Steudel; Dr. Yana Drozdova
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Article
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2006
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John Wiley and Sons
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English
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Ab initio MO calculations (MP2/6-311 G\*\*//HF/6-311 G\*\*) have been performed for several isomers (including rotamers) of Me,S,O and Me,S,O,. MeS(0)SSMe exists as five ro- tamers; the most stable form (la) has a helical backbone CSSSC with S-S bond lengths of 206.0 (S"S") and 212.4 pm (S"S"'). The