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Chemistry of the Si−Si and Fe−Fe Bonds in the Cyclic Structure (Me 2 SiSiMe 2 )[η 5 -C 5 H 4 Fe(CO) 2 ] 2 . Selective Cleavage of the Fe−Fe Bond by I 2 and Unexpected Properties of the Iodide

✍ Scribed by Sun, Huailin; Zhang, Zhensheng; Pan, Yanbin; Yang, Jian; Zhou, Xiuzhong


Book ID
126191709
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
153 KB
Volume
42
Category
Article
ISSN
0020-1669

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Cleavage of the Fe–Fe Bond of (Me2SiSiMe
✍ Hud-Lin Sun; Zhen-Sheng Zhang; Xiu-Zhong Zhou 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 327 KB 👁 1 views

## Abstract The reaction of the title cyclic complex (1) with sodium amalgam in THF resulted in the expected cleavage of the Fe—Fe bond to afford bis‐sodium salt (Me~2~SiSiMe~2~) [η^5^‐C~5~H~4~Fe (CO)~2~Na]~2~ (4). The latter was not isolated and was used directly to react with MeI, PhCH~2~Cl, CH~3