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Chemistry of the Ginkgolides. Part 10: Access to 14C-Labelled Ginkgolide A

✍ Scribed by Klaus Weinges; Hartmut Schick; Hermann Irngartinger; Thomas Oeser


Book ID
108370806
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
102 KB
Volume
56
Category
Article
ISSN
0040-4020

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Chemistry of the Ginkgolides, IX. Ozonol
✍ Weinges, Klaus ;Schick, Hartmut ;Irngartinger, Hermann ;Oeser, Thomas 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 214 KB

## Abstract Ozonolysis of (10__R__)‐10‐acetoxy‐3,14‐didehydroginkgolide (1) did not lead to the expected α‐hydroxy ketone 3b. Instead, ring‐opening of the acetal ring C occurred leading, after acetylation, to the spiroacylal 2. Its structure was confirmed by crystal structure analysis.

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