## Abstract Ozonolysis of (10__R__)‐10‐acetoxy‐3,14‐didehydroginkgolide (1) did not lead to the expected α‐hydroxy ketone 3b. Instead, ring‐opening of the acetal ring C occurred leading, after acetylation, to the spiroacylal 2. Its structure was confirmed by crystal structure analysis.
Chemistry of the Ginkgolides. Part 10: Access to 14C-Labelled Ginkgolide A
✍ Scribed by Klaus Weinges; Hartmut Schick; Hermann Irngartinger; Thomas Oeser
- Book ID
- 108370806
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- French
- Weight
- 102 KB
- Volume
- 56
- Category
- Article
- ISSN
- 0040-4020
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📜 SIMILAR VOLUMES
## Abstract Treatment of the enol acetate 3‐acetoxy‐10‐methoxy‐methoxy‐2,3‐didehydro‐14,15,16‐trinorginkgolide^[2^] (2) with potassium osmate/__N__‐methylmorpholine __N__‐oxide in acetone/acetic acid solution did not yield the expected 2‐hydroxy‐3‐oxo derivative 3, but the dimeric ginkgolide (2__S_
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