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Chemistry of singlet oxygen. Synthesis of functionalized cyclopentenones from saturated fulvene endoperoxides

โœ Scribed by Erden, Ihsan; Xu, Fu Pei; Drummond, Jane; Alstad, Roger


Book ID
120498524
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
174 KB
Volume
58
Category
Article
ISSN
0022-3263

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Decomposition of the saturated endoperoxide derived fmm 6-t-butylfulvene at 1OOW gives a stable allene oxide wbicb was isolated and cbaracwized by spcctrosoopy and chemical transformation8. The thermal i8omrization of tbe psrent unsaturated system is also described and the decompo8ition mechanism8 a

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