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Chemistry of singlet oxygen: Isolation and characterization of a stable allene oxide from a fulvene endoperoxide

✍ Scribed by Ihsan Erden; Jane Drummond; Roger Alstad; Fupei Xu

Publisher: Elsevier Science
Year: 1993
Tongue: French
Weight: 266 KB
Volume: 34
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)91767-2

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✦ Synopsis

Decomposition of the saturated endoperoxide derived fmm 6-t-butylfulvene at 1OOW gives a stable allene oxide wbicb was isolated and cbaracwized by spcctrosoopy and chemical transformation8. The thermal i8omrization of tbe psrent unsaturated system is also described and the decompo8ition mechanism8 are dkcussed.

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