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Chemistry of singlet oxygen. 44. Mechanism of photooxidation of 2,5-dimethylhexa-2,4-diene and 2-methyl-2-pentene

โœ Scribed by Manring, Lewis E.; Foote, Christopher S.


Book ID
125991163
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
1002 KB
Volume
105
Category
Article
ISSN
0002-7863

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Singlet oxygenation of cycloocta-1,3,5-t
โœ Waldemar Adam; Ihsan Erden ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 216 KB

Photosensitized singlet oxygenation of 1,3,5-cyclooctatriene affords the (4.2.2)-and (2.2.2)-type endoperoxides, which were reduced with diimide, thermally isomerized, and deoxygenated with triphenylphosphine. Cycloocta-1,3,5-triene (k) is a versatile substrate for cycloaddition in view of its dive