Reactions in the gas phase of the 13-and lklectron radical anions [Cr(CO),]-' and [Cr(CO),]-\* with a series of 27 aldehydes, ketones, esters and ethers have been examined. Sequential alkane eliminations and metal-bonded CO ligand displacements were the principal reactions identified for the RCHO/[C
✦ LIBER ✦
Chemistry of electron deficient organometallic anions: gas phase reactions of [Cr(CO)3]−· with amines
✍ Scribed by I.K. Gregor
- Book ID
- 108325056
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 285 KB
- Volume
- 132
- Category
- Article
- ISSN
- 0020-1693
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