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Chemistry of electron deficient organometallic anions: gas phase reactions of [Cr(CO)3]−· with amines

✍ Scribed by I.K. Gregor


Book ID
108325056
Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
285 KB
Volume
132
Category
Article
ISSN
0020-1693

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📜 SIMILAR VOLUMES


Gas-phase chemistry of electron deficien
✍ I. K. Gregor 📂 Article 📅 1989 🏛 John Wiley and Sons 🌐 English ⚖ 432 KB

Reactions in the gas phase of the 13-and lklectron radical anions [Cr(CO),]-' and [Cr(CO),]-\* with a series of 27 aldehydes, ketones, esters and ethers have been examined. Sequential alkane eliminations and metal-bonded CO ligand displacements were the principal reactions identified for the RCHO/[C

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The reaction of Cr( CO)s with 0 ("P) atoms was studied in an isothermal discharge-flow reactor with He and Ar as a main carrier gas. 0 atoms were produced by discharging Os/He mixtures. The species in the flow system were detected with a quadrupole mass spectrometer via a molecular-beam system. The