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Chemistry of bent bonds. XXVIII. Transition metal complex specificity and sutstituent effects in the transition metal complex promoted rearrangement of phneyl-substituted bicyclo [1.1.0]butanes

✍ Scribed by Gassman, Paul G.; Nakai, Takeshi

Book ID
120285794
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
923 KB
Volume
94
Category
Article
ISSN
0002-7863

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7-Methyl-frans-bicyclo[4LO]hept-3-ene has been synthesized and the thermal and transitionmetal-complex promoted rearrangements of trans-bicyclo[4.1.0]hept-3-ene, 7-methyl-franr-bicyclo[4.1.0]-hept3-ene, and 7,7-dimethyl-tranr-bicyclo[4.l.O]hept-3-ene have been compared.