𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Chemistry and biochemistry of 1-desoxysphinganine 1-phosphonate (dihydrosphingosine-1-phosphonate)

✍ Scribed by Wilhelm Stoffel; Michael Grol

Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
629 KB
Volume
13
Category
Article
ISSN
0009-3084

No coin nor oath required. For personal study only.

✦ Synopsis

Dedicated to

📜 SIMILAR VOLUMES

Efficient synthesis of sphingosine-1-pho
Efficient synthesis of sphingosine-1-phosphonate and homo-sphingosine-1-phosphonate
✍ Andrej Tarnowski; Thomas Bär; Richard R Schmidt 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 190 KB

Sphingosine can be selectively transformed into 2-N,3-O-protected 1-O-mesyl derivative 8. Transformation into the bromide, Michaelis-Arbusov reaction with trimethyl phosphite, and then removal of all protective groups with LiOH afforded sphingosine-l-phosphonate (4) in high overall yield. Chain exte

[1-(Hydroxy­ethyl­ammonio)propyl]phospho
[1-(Hydroxy­ethyl­ammonio)propyl]phospho­nate
✍ Shivachev, Boris ;Petrova, Rosica ;Kossev, Krassimir ;Troev, Kolio 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 320 KB

Single-crystal X-ray study T = 290 K Mean '(C±C) = 0.005 A Ê R factor = 0.042 wR factor = 0.123 Data-to-parameter ratio = 16.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

[2-(Dimethyl­sulfonio)-1-hydr­oxy-1-phos
[2-(Dimethyl­sulfonio)-1-hydr­oxy-1-phosphono­ethyl]phospho­nate monohydrate
✍ Zhang, Yonghui ;Cao, Rong ;Hudock, Michael P. ;Wilson, Scott R. ;Oldfield, Eric 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 234 KB

In the title crystal structure, C 4 H 12 O 7 P 2 SÁH 2 O, the sulfonium groups have a pyramidal geometry and bridging water molecules form a complex three-dimensional hydrogen-bond network involving neighboring phosphonate groups.