ChemInform Abstract: α-Phosphoryl Sulfoxides. Part 10. A General Synthesis of Optically Active α-Chlorovinyl Sulfoxides.
✍ Scribed by M. MIKOLAJCZYK; J. A. KRYSIAK; W. H. MIDURA; M. W. WIECZOREK; J. BLASZCZYK
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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Synthesis of α,β-Unsaturated Sulfoxides and Aryl 1,2-x-Fused onto Furan Rings. -ortho-Quinones react non-uniformly with α-phosphoryl sulfoxide (II) to furnish mono-olefins [cf. (III)] or fused dihydrofuran derivatives [cf. (V), (VII)]. Contrary, the p-quinones (VIII) react with (II) in the usual ma