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ChemInform Abstract: α-Oxosulfines. Part 3. Generation and Trapping of α- Oxothioaldehyde S-Oxides.

✍ Scribed by G. CAPOZZI; A. CORTI; S. MENICHETTI; C. NATIVI

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: α-Oxosulfines. Part
ChemInform Abstract: α-Oxosulfines. Part 2. The First Example of ortho-Thioquinone-S- oxides.
✍ G. CAPOZZI; P. FRATINI; S. MENICHETTI; C. NATIVI 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 36 KB

Part 2. The First Example of ortho-Thioquinone-Soxides. -Stereoselective oxidation of sulfides such as (III), (VIII), or (X) gives the oxathiin-S-oxides (IV), (V), (IX), (XI), and (XII). Retro Diels-Alder reactions of these S-oxides lead to the reactive title intermediates of type (XIII), which can