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ChemInform Abstract: α-Ketenyl Radical Intermediates in the Synthesis of Propellanes. A Formal Synthesis of Modhephene.

✍ Scribed by B. DE BOECK; G. PATTENDEN

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: A Formal Synthesis
ChemInform Abstract: A Formal Synthesis of (-)-α-Kainic Acid.
✍ J. COSSY; M. CASES; D. GOMEZ PARDO 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 42 KB 👁 1 views

A Formal Synthesis of (-)-α-Kainic Acid. -Starting from Lpyroglutamic acid (-)-(I), the known precursor (-)-(XVI) for the synthesis of the title compound is presented. The key step in this approach is the SmI 2 -mediated ketyl radical cyclization of the enecarbamate (X). Under irradiation condition