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ChemInform Abstract: ZrOCl2 Catalyzed Chemoselective Conversion of Aldehydes to geminal-Diacetates and Their Cleavage: A Mild and Efficient Method.

✍ Scribed by Adki Nagaraj; Cherkupally Sanjeeva Reddy

Publisher
John Wiley and Sons
Year
2008
Weight
42 KB
Volume
39
Category
Article
ISSN
0931-7597

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ZrOCl2 Catalysed Chemoselective Conversi
ZrOCl2 Catalysed Chemoselective Conversion of Aldehydes to geminal-Diacetates and Their Cleavage: A Mild and Efficient Method
✍ Adki NAGARAJ; Cherkupally SANJEEVA REDDY πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 61 KB πŸ‘ 1 views

## Abstract ZrOCl~2~ was found to be an effective Lewis acid catalyst for the solventless chemoselective conversion of aldehydes into geminal‐diacetates in high yields at room temperature. Regeneration of the aldehydes from the acetals was also achieved using the same catalyst in water. The benefic