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ChemInform Abstract: A Mild and Efficient Cleavage of gem-Diacetates to Aldehydes by CBr4.

✍ Scribed by T. Ramalingam; R. Srinivas; B. V. Subba Reddy; J. S. Yadav

Publisher: John Wiley and Sons
Year: 2010
Weight: 29 KB
Volume: 32
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200142081

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## Abstract ZrOCl~2~ was found to be an effective Lewis acid catalyst for the solventless chemoselective conversion of aldehydes into geminal‐diacetates in high yields at room temperature. Regeneration of the aldehydes from the acetals was also achieved using the same catalyst in water. The benefic