ChemInform Abstract: ZnCl2-Catalyzed Hydrodefluorination of gem-Difluoromethylene Derivatives with Lithium Aluminum Hydride.
โ Scribed by Jianhang Cheng; Jingjing Wu; Song Cao
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 34 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Nickel-Catalyzed Hydrodefluorination of Fluoroarenes and Trifluorotoluenes with Superhydride (Lithium Triethylborohydride). -Two new catalyst systems are developed. Fluoroarenes and ฮฑ,ฮฑ,ฮฑ-trifluorotoluene derivatives are reduced by the combination of 40 mol% NiCl2 and LiBHEt3 to afford the correspon
A Mild Chemospecific Reductive Dehalogenation of Ethylaminobenzamides with Lithium Aluminum Hydride. -Secondary N-(2aminoethyl)benzamides substituted at the ortho-position of the phenyl ring with halogen are dehalogenated at this position by treatment with LiAlH 4 at room temperature. The p-iodo de