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ChemInform Abstract: Zintl-Compounds with Gold: M3AuSn4 with M: K, Rb, Cs and M3AuPb4 with M: Rb, Cs.

✍ Scribed by U. ZACHWIEJA; J. MUELLER; J. WLODARSKI

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Jahn-Teller Orderin
ChemInform Abstract: Jahn-Teller Ordering in Kagome-Type Layers of Compounds M2Mβ€²MnIII3F12 ( M: Rb, Cs; Mβ€²: Li, Na, K).
✍ U. ENGLICH; C. FROMMEN; W. MASSA πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 29 KB πŸ‘ 1 views

prepared by heating mixtures of the binary fluorides. Single-crystal XRD results show that the compounds with M2M': Cs2Na, Rb2Na, and Rb2Li are isostructural and crystallize in the triclinic space group P1 with Z = 2. Cs2LiMn3F12 (trigonal, R3, Z = 3) is a merohedral twin and Cs2KMn3F12 belongs to t