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ChemInform Abstract: Zeolite Catalyzed Ring Opening of Epoxides to Acetylated Diols with Acetic Anhydride.

✍ Scribed by P. Ramesh; V. L. Niranjan Reddy; D. Venugopal; M. Subrahmanyam; Y. Venkateswarlu

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
32
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Lanthanoid-Catalyze
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Lanthanoid-Catalyzed Ring-Opening Reaction of Epoxides with Acyl Halides. -Eu(dpm) 3 is found to be the best reagent for ring-opening reaction of epoxides with acyl halides. In the case of cyclohexene oxide (I), a trans addition produces (III) stereoselectively. Propylene oxide affords a mixture of