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ChemInform Abstract: (Z)-(2-Bromovinyl)-MIDA Boronate: A Readily Accessible and Highly Versatile Building Block for Small Molecule Synthesis.

✍ Scribed by Eric M. Woerly; Justin R. Struble; Nagarjuna Palyam; Sean P. O'Hara; Martin D. Burke

Publisher: John Wiley and Sons
Year: 2011
Weight: 58 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201142172

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✦ Synopsis

Abstract

The synthesis of the bifunctional (Z)‐olefin building block (II) is developed and the utility the product in a variety of Pd‐catalyzed cross‐coupling reactions is demonstrated.

📜 SIMILAR VOLUMES

ChemInform Abstract: Ethynyl MIDA Borona

ChemInform Abstract: Ethynyl MIDA Boronate: A Readily Accessible and Highly Versatile Building Block for Small Molecule Synthesis.

✍ Justin R. Struble; Suk Joong Lee; Martin D. Burke 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 47 KB 👁 2 views

## Abstract Ethynyl N‐methyliminodiacetic acid boronate (I) is successfully applied in the regioselective iterative synthesis of arylethyne (III) and tolan derivatives, e.g. (IV).